I think compression socks (or any compression clothing) is helpful for any activity involving physical exertion. But I doubt those from this skate company are anything special that you can't find at a dedicated sporting good store for 1/2 the price. I would try a pair but not at $25.
Edit:
Some Reddit research indicated compression clothing for sports doesn't get tight enough.
"Studies show that when working out, the only thing compression does is reduce vertical oscillation (bouncing up and down when running) which means you won't really get that one specific benefit unless you're wearing full-length compression tights.
On the other hand, compression aids in recovery. The increased circulation brings increased blood flow which helps rebuild tissue (I think).
My opinion is, wear them during running if you think they're comfortable. Wear them after for the benefits."
Worth checking out if I wasn't already wearing 2 knee guards under my pants, I'd start feeling like a wrapped up Christmas present.