Yes, anything south of the Pyrenees or the Alps is good for skating in February.
However, one should also consider the pretty amazing indoor parks in Denmark, Sweden and Finland as well. Bryggeriet in Malmhe Stockholm skatepark or the few indoors in Helsinki, combined with a winter experience (sauna, party life as much as Covid allows) is a pretty cool and different thing to do, other than joining the skate/insta fame crowds in Barcelona.